It was a repeat of the U.S. Open semifinal when the 26-year-old Zvonareva eliminated the Dane 6-4, 6-3 to finish runner-up of the Grand Slam tournament.
The Russian remained sharp when the Monday'match started, breaking Wozniacki in the third game to took a 2-1 lead.
Wozniacki, who just overtook Serena Williams to seize the top position of the WTA rankings after passed the third round of China Open, gradually controlled the rhythm and broke the opponent in the sixth and eighth games respectively.
As Zvonareva's forehand return went out of the baseline in the ninth game, the first seed finished off the opening set 6-3.
Zvonareva was more familiar with the Lotus court, as the Russian won a bronze medal during the 2008 Beijing Olympic Games, which were also held in the National Tennis Certer in Beijing. She rallied to fight back in the second set, converting her sole break opportunities while leaving no chance of break to the Dane in the whole set.
The match remained close when it came to the final set. Wozniacki seized her only chance of break in the second game, taking the first Premier Mandatory title in her career after clinching the two hours, four minutes victory.